(CuI)3P4Se4: β-P4Se4Cages between Columns of Copper Iodide†
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چکیده
منابع مشابه
Geometry flexibility of copper iodide clusters: variability in luminescence thermochromism.
An original copper(I) iodide cluster of novel geometry obtained by using a diphosphine ligand is reported and is formulated [Cu6I6(PPh2(CH2)3PPh2)3] (1). Interestingly, this sort of "eared cubane" cluster based on the [Cu6I6] inorganic core can be viewed as a combination of the two known [Cu4I4] units, namely, the cubane and the open-chair isomeric geometries. The synthesis, structural and phot...
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The colorless complexes [Cu(py)I], and [Cu(mor)I], (py = pyridine; mor = morpholine) were shown to be photoluminescent in noncoordinating solvents such as benzene, CH2Cl2, or acetone at room temperature. The red emission (A, = 698 nm) of the pyridine complex in benzene is quite intense (a = 0.04) and decays with a lifetime of T = 0.9 X s. The red photoluminescence (A,, = 654 nm) of the morpholi...
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Oxidative nitroalkylation of β-ketoamides and nitroalkanes, mediated by hypoiodide generated from tert-butyl hydrogen peroxide and a catalytic amount of guanidinium iodide, afforded the corresponding α-nitroalkyl-β-ketoamides in up to 97% yield.
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Micrometer copper columns were fabricated via a technology named localized electrochemical deposition (LECD). This paper studies the effects of applied potential and the initial gap between electrodes on the LECD process. The surface and cross sectional morphologies, as well as the average deposition rate were investigated to evaluate the quality of the deposited copper columns. Results demonst...
متن کاملDistribution of iodide between cells and plasma as measured by means of radioactive iodide.
Scott, Reavis, Saunders, and White (1) have proposed a method of evaluating thyroidal function which depends upon knowledge of the distribution of iodide between erythrocytes and plasma in the blood. Their proposal is based upon the statement that the ratio C&/Cl, = 1,/I, = 0.5, where the subscripts c and p refer to cells and plasma, respectively. Earlier, Rall, Power, and Albert (2) had indica...
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ژورنال
عنوان ژورنال: Inorganic Chemistry
سال: 1999
ISSN: 0020-1669,1520-510X
DOI: 10.1021/ic981042f